Steklo i Keramika (Glass and Ceramics). Monthly scientific, technical and industrial journal

 

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Silica-phosphorous-antimonic ionites and their use in glass hardening bath-furnaces

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Autors: Mikulo R. V., Solinov V. F., Sinyakova M. A., Karmanova L. A., Emelyanov G. A., Chernik G. G.
  • Continuous numbering: 1064
  • Pages: 10-14
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Heading: Science for glass production

It was found that the samples of silicon-phosphorus-antimony ion exchangers obtained in the volumes of pilot batches are similar in properties to the samples obtained under laboratory conditions, and show identical characteristics during the regeneration of the potassium nitrate melt. In order to optimize the process of ion-exchange glass hardening, it is proposed to introduce two ion exchangers into the melt: K [Sb (OH) 6 ] for the sorption of Na + ions and silicophosphorus-antimony ion exchanger for polyvalent impurity ions
Cand. tech. Sci. R. V. MIKULO1, Dr. Tech. Sci. V. F. SOLINOV 1 ( e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it. ), Cand. chem. Sciences M. A. SINYAKOVA 2 ( e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it. ), L.A. KARMANOVA 2 , Dr. Sciences G. A. Emelyanov 3 , Cand. chem. sciences G. G. CHERNIK 4 ; 1 JSC "Scientific Research Institute of Technical Glass" (JSC "NITS") (Russia, Moscow)
2 FGBOU VO "St. Petersburg State University "(Russia, St. Petersburg)
3 FSUE" Scientific Research Institute of Synthetic Rubber named after Academician S. V. Lebedev "(FSUE" NIISK ") (Russia, g. Petersburg)
4 LLC "ACTIV-NANO" (Russia, St. Petersburg)
Butaev A.M. Glass strength. Ion exchange hardening. Makhachkala, 1997.253 p. Nikonorov N.V., Evstropyev E.K. Optical materials science: fundamentals of the strength of optical glass. SPb .: ITMO, 2009.102 p. Boguslavsky I. A., Mikulo R. V. Interaction of forward and backward connections science? technology for creating the process of ion-exchange glass hardening // Glass and ceramics. 1979.? 8.S. 5? 8. ? Boguslavskii IA, Mikulo RV Direct and feedback connections between research and production in the transfer of the process of ion-exchange strengthening of a glass from laboratory to factory // Glass and Ceram. 1979. V. 36. N 8. P. 423? 428.? Ayler R. Chemistry of Silica. Moscow: Mir, 1982. Part 2. 931 p. Wakatsuki T., Wakatsuki T., Furukawa H., Kawaguchi K. Specific and non-specific adsorption of inorganic ions // Soil. Sci, Plant, Nutr. Tokyo. 1974. N 20. R. 353. Mikulo RV Research in the field of intensification of processes of ion-exchange hardening of large-sized glasses for the creation of high-strength products of structural optics: dis. ? Cand. tech. sciences. Moscow: NITS, 1985.195 p. Remy G. Course in Inorganic Chemistry. Moscow: Foreign Literature Publishing House, 1963.718 p. Grigorova N.S., Nikolsky B.P., Belinskaya F.A., Kozhina I.I. Ser. 4. Physics and chemistry. 1981. Issue. 10, p. 79? 86. Grigorova NS, Belinskaya FA, Militsina EA Ion-exchange properties of silicon-phosphorus-antimony cation exchangers // Ion exchange and ionometry. L .: Leningrad State University, 1976. Issue. 1.P. 81? 88. Antuganova Yu. O., Sinyakova MA Kinetics of metal ion exchange on silicon-phosphorus-antimony ion exchanger // Ecological chemistry. 2016.Vol. 25. Iss. 2.S. 63? 67. GOST 19790? 74. Technical potassium nitrate (technical potassium nitrate). M., 1974 . THE USSR ? 826679, cl. From 03c 21/00. Bath for hardening glass products / I. A. Boguslavsky, R. V. Mikulo, F. A. Belinskaya et al. M., 1981.

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Keywords

glass hardening, ion exchange, inorganic ion exchangers

Use the reference below to cite the publication

Mikulo R. V., Solinov V. F., Sinyakova M. A., Karmanova L. A., Emelyanov G. A., Chernik G. G. Silica-phosphorous-antimonic ionites and their use in glass hardening bath-furnaces. Steklo i keramika. 2016:89(8):10-14. (in Russ). UDK 666.1.031.2: 544.726:666.1.039.2
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Lyudmila Vladimirovna Sokolova