Steklo i Keramika (Glass and Ceramics). Monthly scientific, technical and industrial journal

 

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Structure and SO3 ions structural state in sulphate-containing glasses (a review)

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Autors: Bobkova N. M., Trusova E. E.
  • Continuous numbering: 1073
  • Pages: 7-11
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Heading: Science for glass production

A review of the literature data on sulfate-containing glasses in silicate, borate, and phosphate systems is presented. Experimental data confirm the finding of the [SO 4 ] 2- group in an isolated state in all systems, however, the possible amount of SO 3 contained in the glass is increases significantly when passing from silicate to borate and phosphate systems
Dr. Tech. Sciences N. M. BOBKOVA ( e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it. ), Cand. tech. Sciences E. E. Trusova ( e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it. ); Educational institution & # 171; Belarusian State Technological University & # 187; (BSTU) (Belarus, Minsk)
Pankova N.A. Investigation of the mechanisms of the clarification process from teclomass in industrial conditions: dis. ? Dr. tech. sciences. M., 1976.34 p. Pankova N.A., Levitin L.Ya. Influence of the composition of the gaseous medium of glass-melting furnaces on the solubility of gases in sheet glass // Glass Physics and Chemistry. 1076.Vol. 2.? 2.S. 162? 170. Preston E., Turner W., Laitwaite H. Study on the volatization of sulfate from soda lime silica glasses // J. Soc. Glass Techn. 1936. V. 20. N 79. P. 127? 138. Bezborodov MA Study of the solubility of sulfuric anhydride in glass // DAN BSSR. 1955.? 3.S. 63? 75. Chemical technology of glass and sitalls / ed. N. M. Pav-lushkina. M., 1983.427 p. Merker L., Wondratschek H. Einige phisikalische Eigen-schaften von Bleisilikat? Glasern mit Hohen Sulphatenhalt // Glastechn. Ber. 1959. Bd. 32. N 2. S. 54? 58. Galant EI Sulphate-containing glasses // Optical mechanics. prom. 1962.? 3.S. 26? 31. Milyukov E. M., Kasymova S. S. Non-mixing melts and glass. Tashkent, 1981.176 p. Appen A.A. Glass chemistry. M., 1974.S. 220? 221. Rapan R., Chetyanu I. Inorganic chemistry. M., 1971.560 p. Stefanovskii S.V., Lifanov F.A.Glass formation in the systems Na2O (PbO)? SiO2 (B2O3, P2O5)? SO3 // Glass Physics and Chemistry. 1987. T. 13.? 2.P. 299? 302. Kolesova VA, Ignatieva IS, Kalinina NE On sulfate groups in the networks of alkali-sulfate-silicate glasses // Glass Physics and Chemistry. 1976. T. 2.? 5.S. 400? 404. Papadopoulos K. The solubility of SO3 in soda lime silica melts // Phys. Chem. Glasses. 1973. V. 14. N 3. P. 60? 65. Stefanovskii SV, Kochetkova EI, Sokolova NP The structure of glasses in the systems Na2O? SiO2 (P2O5)? SO3 // Glass Physics and Chemistry. 1989. T. 15.? 1.S. 57? 61. Arkhipov VG, Ivanova LV, Malyutin VL et al. Spectrooptical study of the structural features of alkali-containing sulfate-phosphate glasses // Journal of Applied Chemistry. 1986. T. 45.? 3.S. 460? 464. Kolesova VA Lithium-sulfate-borate glasses of composition 2Li2O? 3B2O3? XSO3 // Glass Physics and Chemistry. 1986. T. 12.? 1.P. 106? 108. Zahis M., Oleazcuaga R., Hagenmuller P. Synthese et conductive de verres du systeme B2O3? Na2O? Na2SO4 // Mater. Res. Bull. 1982. V. 17. N 2. P. 217? 222. Kolesova VA, Kalinina NE Comparative studies of the structure of glasses in the PbO SO3 SiO2 system // Glass Physics and Chemistry. 1977. T. 3.? 4.S. 324? 327.

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Keywords

sodium sulfate, sulfate glasses, silicate glasses, borate glasses, phosphate glasses

Use the reference below to cite the publication

Bobkova N. M., Trusova E. E. Structure and SO3 ions structural state in sulphate-containing glasses (a review). Steklo i keramika. 2017:90(5):7-11. (in Russ). UDK 666.1
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Lyudmila Vladimirovna Sokolova