Consolidation of industrial silicon carbide powder was carried out using a spark plasma sintering unit. It has been shown that preliminary mechanical activation is a promising method for introducing a high content of boron additives into silicon carbide. The effect of the amount of boron additive on sintering, microstructure and properties of ceramic material has been studied. The obtained ceramics based on silicon carbide with a mass content of 10 & # 37; boron with a density of 3.12 g / cm 3 , a hardness of 31.9 GPa and a fracture toughness factor of 5.65 MPa • m 1/2 , promising for use as a structural material in nuclear reactors and gas turbine engines
S. Yu. MODIN 1,2 , N. A. POPOVA 1 , Cand. tech. Sciences Yu. E. LEBEDEVA 2 (This email address is being protected from spambots. You need JavaScript enabled to view it.), Cand. tech. Sciences A. S. CHAINIKOVA 2 , Cand. tech. D. V. GRASHCHENKOV 2 , I. V. OSIN 2 , Cand. tech. D.O. LEMESHEV 1 ; 1 Federal State Budgetary Educational Institution of Higher Education & # 171; Russian Chemical-Technological University named after V.I. D. I. Mendeleev & # 187; (RKhTU named after D. I. Mendeleev) (Russia, Moscow) 2 FSUE & # 171; All-Russian Research Institute of Aviation Materials & # 187; State Scientific Center of the Russian Federation (FSUE & # 171; VIAM SSC RF & # 187;) (Russia, Moscow)
Kablov E. N., Grashchenkov D. V., Isaeva N. V. et al. Promising high-temperature ceramic composite materials // Russian Chemical Journal. 2010. T. LIV. ? 1.S. 20? 24.
Sevastyanov V.G., Simonenko E.P., Grashchenkov D.V. et al. Obtaining whiskers of silicon carbide using the sol-gel method in the bulk of SiC-ceramics // Composites and nanostructures. 2014. T. 6.? 4.S. 198? 211.
Kablov E. N. Composites: today and tomorrow // Metals of Eurasia. 2015.? 1.P. 36? 39.
Chainikova AS, Vaganova ML, Shchegoleva NE, Lebedeva Yu. E. Technological aspects of creating radio-transparent glass-crystalline materials based on high-temperature aluminosilicate systems // Tr. VIAM: electron. scientific and technical zhurn. 2015.? 12. Art. 04. URL: http://www.viam-works.ru (date of access 10.12.2016). dx.doi.org/10.18577/2307-6046-2015-0-11-4-4.
Lebedeva, Yu. E., Popovich, NV, Orlova, LA, Protective high-temperature coatings for composite materials based on SiC, Tr. VIAM: electron. scientific and technical zhurn. 2013.? 2. Art. 06. URL: http://www.viam-works.ru (date of access 10.12.2016).
Lebedeva, Yu. E., Grashchenkov, DV, Popovich, NV, et al. Development and study of thermostable coatings obtained by the sol-gel method in the Y2O3? Al2O3? SiO2 system for SiC-containing materials, Tr. VIAM: electron. scientific and technical zhurn. 2013.? 12. Art. 03. URL: http://www.viam-works.ru (date of access 10.12.2016).
Katoh Y., Snead LL, Henager CH Current status and critical issues for development of SiC composites for fusion applications // Journal of nuclear materials. 2007. V. 367? 370. R. 659? 671.
Gu H., Shinoda Y., Wakai F. Detection of boron segregation to grain boundaries in silicon carbide by spartially resolved electron energy-loss spectroscopy // J. Am. Ceram. Soc. 1999. V. 82. N 2.P. 469? 472.
Malinge A., Coupe A., Le Petitcorps Y., Pailler R. Pressureless sintering of beta silicon carbide nanoparticles // Journal of the European ceramic society. 2012. V. 32. P. 4393? 4400.
Elzbieta E., Ptak W., Stobierski L. Influence of sintering activators on structure of silicon carbide // Solid State Ionics. 2001. V. 141? 142. P. 523? 528.
Ray DA, Kaur S., Cutler RA Effect of additives on the activation energy for sintering of silicon carbide // J. Am. Ceram. Soc. 2008. V. 91 [4]. P. 1135? 1140.
Barick P., Chakravarty D., Saha BP Effect of pressure and temperature on densification, microstructure and mechanical properties of spark plasma sintered silicon carbide processed with? -Silicon carbide nanopowder and sintering additives // Ceramics International. 2016. V. 42. P. 3836? 3848.
Torresillas San Millan R., Solis Pinargote NV, Okunkova AA, Peretyagin P. Yu. Fundamentals of the process of spark plasma sintering of nanopowders. Moscow: Tekhnosfera, 2014.96 p.
Niihara KA Fracture mechanics analysis of indentation-induced Palmqvist crack in ceramics // J. Mater. Sci. Lett. 1983. V. 2. P. 221? 223.
Avvakumov EG, Gusev AA Mechanical methods of activation in the processing of natural and technogenic raw materials. Novosibirsk: Geo, 2009.155 p.
Kablov E. N. Innovative developments of FSUE? VIAM? SSC RF for the implementation of? Strategic directions for the development of materials and technologies for their processing for the period up to 2030? // Aviation materials and technologies. 2015.? 1 (34). S. 3? 33. DOI: 10.18577 / 2071-9140-2015-0-1-3-33.
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