Calcium phosphate powder was synthesized from calcium formate Ca (CHO 2 ) 2 and ammonium hydrogen phosphate (NH 4 ) 2 HPO 4 at the Ca / P ratio in the initial aqueous solutions equal to 1. The phase composition of the powders synthesized from solutions with a concentration of 0.5 M was represented by brushite CaHPO 4 .2H 2 O and octacalcium phosphate Ca 8 (NPO 4 ) 2 (PO 4 ) < sub> 6 · 6Н 2 O. The phase composition of the powder after firing at 1100 & # 176; C was represented by calcium pyrophosphate & # 946; -Ca 2 P 2 O 7 and tricalcium phosphate & # 946; -Ca 3 (PO 4 ) 2 . The synthesized powder can be used to obtain biocompatible resorbable biphasic ceramic materials and composites with a polymer matrix.
1. Barinov SM Ceramic and composite materials based on calcium phosphates for medicine // Advances in chemistry. 2010.Vol. 79.?. 1.S. 15? 32.
2. Safronova TV, Putlyaev VI Medical inorganic materials science in Russia: calcium phosphate materials // Nanosystems: physics, chemistry, mathematics. 2013. T. 4.? 1.S. 24? 47.
3. Belyakov AV, Zharikov EV, Malygin AA Chemical foundations of nanotechnology of solid-phase materials for various functional purposes: textbook. allowance. SPb .: SPbGTI (TU), 2006.103 p.
4. Safronova TV Phase composition of ceramics based on calcium hydroxyapatite powders containing by-products of the synthesis reaction. Glass and Ceramics. 2009.? 4.S. 21? 24.
? Safronova TV Phase composition of ceramic based on calcium hydroxyapatite powders containing byproducts of the synthesis reaction // Glass and Ceram. 2006. V. 66. N 3? 4. P. 136? 139.?
5. Safronova TV, Shekhirev MA, Putlyaev VI, Tretyakov Yu. D. Ceramic materials based on hydroxyapatite synthesized from solutions of various concentrations // Inorganic materials. 2007. T. 43.? 8.C. 1005? 1014.
6. Safronova TV, Putlyaev VI, Kazakova GK, Korneichuk SA Two-phase ceramics in the CaO? P2O5 system based on a powder synthesized from calcium acetate and ammonium hydrogen phosphate // Glass and Ceramics ... 2013.? 2.C. 34? 41.
? Safronova TV, Putlyaev VI, Kazakova GK, Kornei-chuk SA Biphase CaO? P2O5 ceramic based on powder synthesized from calcium acetat and ammonium hydrophosphate // Glass and Ceram. 2013. V. 70. N 1? 2.P. 65? 70.?
7. Safronova TV, Kazakova GK, Evdokimov PV et al. Ceramics based on calcium phosphate powder synthesized from calcium sucrose and ammonium hydrogen phosphate // Materials Science. 2016.? 3.C. 46? 50.
8. Stepuk AA, Veresov AG, Putlyaev VI, Tretyakov Yu. D. Influence of NO3-, CH3COO- and Cl- anions on the morphology of calcium hydroxyapatite crystals // Reports of the Academy of Sciences. 2007. T. 412.? 1.S. 11? 14.
9. Safronova TV, Kurbatova SA, Shatalova TB et al. Calcium pyrophosphate powder synthesized from pyrophosphoric acid and calcium acetate to obtain bioceramics // Materials Science. 2016.? 8.C. 46? 50.
10. Safronova TV, Putlyaev VI, Evdokimov PV et al. Black powders of calcium phosphates for stereolithography // Coll. tr. XIII Russian-Chinese Symposium? New Materials and Technologies ?. T. 2.M .: Interkontakt Nauka, 2015.S. 604? 606.
11. Safronova TV, Kuznetsov AV, Korneychuk S. et al. Calcium phosphate powders synthesized from solutions with [Ca2 +] / [PO4 3-] = 1 for bioresorbable ceramics // Cent. Eur. J. Chem. 2009. V. 7. N 2. P. 184? 191.
12. Kanazawa T. Inorganic phosphate materials: trans. with jap. Kiev: Nauk. Dumka, 1998.298 p.
13. Pat. 2456253 RF. Method of preparation of a charge for obtaining ceramic biodegradable material / V. I. Putlyaev, T. V. Safronova, E. V. Kukueva, Yu. D. Tretyakov; publ. 20.07.2012.
14. Kuznetsov V. I., Globus R. L., Karskaya T. N. et al. Chemical reagents and preparations: a reference book. Moscow: Goskhimizdat, 1953.672 p.
15. Pat. 6667049 US. Relic process for producing bioresorbable ceramic tissue scaffolds / VF Janas, K. Sh. TenHuisen. 12/23/2003.
16. Pat. 4752457 US. Method for production of porous spheres of calcium phosphate compound / T. Motohiro, K. Sukezo. 06/21/1988.
17. Yasukawa A., Takase H., Kandori K., Ishikawa T. Preparation of calcium hydroxyapatitie using amides // Polyhedron. 1994. V. 13. N 22. P. 3071? 3078.
18. Wilson RM, Elliott JC, Dowker SEP Formate incorporation in the structure of Ca-deficient apatite: Rietveld structure refinement // Journal of Solid State Chemistry. 2003. V. 174. P. 132? 140.
19. Putlyaev VI, Kukueva EV, Safronova TV et al. Features of octacalcium phosphate thermolysis // New refractories. 2013.10.S. 52? 56.
The article can be purchased
electronic!
PDF format
700 руб
UDK 666.3:546.41?33?18
Article type:
Biomaterials
Make a request