Thermal Transformations in Hardening Compositions Based on Hydroxyapatite, Monocalcium Phosphate Monohydrate and Polymeric Binders

Cand. chem. sciences O. N. MUSSKAYA ¹ ( e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it. ), Cand. chem. VK KRUTKO ¹ , Dr. Sciences A. I. KULAK ¹ , Cand. tech. Sci. T. V. SAFRONOVA ² , Cand. chem. sciences T. B. Shatalova ² ; ¹ Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus (Republic of Belarus, Minsk)
² Lomonosov Moscow State University M. V. Lomonosova (Russia, Moscow)

Musskaya ON, Kulak AI, Krutko VK et al. Obtaining bioactive mesoporous calcium-phosphate granules // Inorganic materials. 2018.Vol. 88.? 2.P. 130? 137. URL: https://doi.org/ 10.7868 / S0002337X18020033 Krut'ko V.K., Musskaya O.N., Kulak A.I., Safronova T.V. Thermal evolution of calcium phosphate foam ceramics obtained on the basis of hydroxyapatite and monocalcium phosphate monohydrate // Physicochemical aspects of the study of clusters, nanostructures and nanomaterials: interuniversity. Sat. scientific. tr. / under total. ed. V. M. Samsonova, N. Yu. Sdobnyakova. Tver: Tversk. state un-t, 2019. Issue. 11, p. 615? 623. URL: https://doi.org/10.26456/pcascnn/2019.11.615 Krutko V.K., Kulak A.I., Musskaya O.N. Thermal transformations in composite materials based on hydroxyapatite and zirconium dioxide // Inorganic materials. 2017.Vol. 53.? 4.S. 427? 434. URL: https://doi.org/10.7868/S0002337X17040091 Smirnov V.V., Khairutdinova D.R., Antonova O.S. et al. Composite cement materials based on calcium sulfate and phosphate for medicine // Reports of the Academy sciences. 2018.Vol. 483.? 2.S. 162? 165. URL: https://doi.org/10.31857/S086956520003473-3 Hirayama S., Takagi S., Markovic M., Chow LC Properties of calcium phosphate cements with different tetracalcium phosphate and dicalcium phosphate anhydrous molar ratios // J. Res. Natl. Inst. Stand. Technol. 2008. V. 113. P. 311? 320. URL: https: // dx.doi.org/10.6028/jres.113.025 Komlev V.S., Fadeeva I.V., Gurin A.N. et al. New calcium phosphate cements based on tricalcium phosphate // Reports of the Academy of Sciences ... 2011.Vol. 437.? 3.S. 366? 369. Liu H., Li H., Cheng W. et al. Novel injectable calcium phosphate / chitosan composites for bone substitute materials // Acta Biomateria. 2006. V. 2. P. 557? 565. URL: https://doi.org/10.1016/j.actbio.2006.03.007 Fomin A.S., Fadeeva I.V., Filippov Ya.Yu. et al. Brushite cement based on? -Tricalcium phosphate for orthopedics // Advanced materials. 2016.? 9, p. 45? 50. Teterina A. Yu., Egorov AA, Fedotov A. Yu. Et al. Bone cements in the calcium phosphate system? chitosan containing magnesium and zinc // Reports of the Academy of Sciences. 2016.Vol. 468.? 4.S. 413? 415. URL: https: // doi.org/10.7868/S0869565216160131 Barinov S.M., Komlev V.S.Calcium phosphate bone cements (review). Part I. Knitting systems // Materials Science. 2014.? 1.S. 33? 40. Musskaya ON, Krutko VK, Kulak AI et al. Calcium phosphate compositions with polyvinyl alcohol for 3D printing // Materials Science. 2019.? 7, p. 23? 28. URL: https://doi.org/10.31044/1684-579X-2019-0-7-23-28 Filippov Ya.Yu., Vlasikhina A.A., Klimashina E.S. et al. Creation of three-dimensional ceramic structures of a given architecture based on the Ca2P2O7? CaNa2P2O7 system // Glass and ceramics. 2018.? 11, p. 35? 39. [Filippov YY, Vlasikhina AA, Klimashina ES et al. Creation of three-dimensional ceramic structures with prescribed architecture based on the system Ca2P2O7? CaNa2P2O7 // Glass Ceram. 2019. V. 75. P. 446? 450. URL: https://doi.org/10.1007/s10717-019-00109-2] Bertol LS, Schabbach R., Santos LAL Dimensional evaluation of patient-specific 3D printing using calcium phosphate cement for craniofacial bone reconstruction // J Biomater. Appl. 2016. V. 31. N. 6. P. 799? 806. URL: https://doi.org/10.1177/0885328216682672 Smirnov V.V. Porous cements for filling bone tissue defects // Materials Science. 2009.? 8, p. 16? 19. Ratier A., ??Freche M., Lacout JL, Rodriguez F. Behavior of an injectable calcium phosphate cement with added tetracycline // Intern. J. Pharm. 2004. V. 274. P. 261? 268. URL: https://doi.org/10.1016/ j.ijpharm. 2004.01.021 Joosten U., Joist A., Gosheger G. et al. Effectiveness of hydroxyapatite-vancomycin bone cement in the treatment of Staphylococcus aureus induced chronic osteomyelitis // Biomaterials. 2005. V. 26. P. 5251? 5258. URL: https://doi.org/10.1016/j.biomaterials.2005.01.001 Musskaya O. N., Kulak A. I., Krutko V. K., Glazov I. E. Adsorption properties of xerogels of calcium phosphates, obtained by liquid-phase synthesis // Physicochemical aspects of the study of clusters, nanostructures and nanomaterials: interuniversity. Sat. scientific. tr. / under total. ed. V. M. Samsonova, N. Yu. Sdobnyakova. Tver: Tversk. state un-t. 2018. Issue. 10, p. 468? 476. URL: https://doi.org/10.26456/pcascnn/2018.10.468 Krut'ko V.K., Kulak A.I., Musskaya O.N. et al. Calcium phosphate foam ceramics based on a powder mixture of hydroxyapatite? Brushite // Glass and ceramics. 2019.? 3.S. 38? 44. [Krut? Ko VK, Kulak AI, Musskaya ON et al. Calcium phosphate foam ceramic based on hydroxy-apatite? Brushite powder mixture // Glass Ceram. 2019. V. 76. no. 3? 4. P. 113? 118. URL: https://doi.org/ 10.1007 / s10717-019-00145-y] Ma Y., Bai T., Wang F. The physical and chemical properties of the polyvinylalcohol / polyvinylpyrroli-done / hydroxyapatite composite hydrogel / / Mater. Sci. Eng. C. 2016. V. 59. P. 948? 957. URL: https://doi.org/ 10.1016 / j.msec.2015.10.081