Steklo i Keramika (Glass and Ceramics). Monthly scientific, technical and industrial journal

 

ISSN 0131-9582 (Online)

  • Continuous numbering: 1166
  • Pages: 55-61
  • Share:

Heading: Not-set

Synthesis and properties data of the ceramic material based on 31.0BaO–30.0B2O3–15.0Al2O3–7.0SiO2–6.8MgO–5.9ZnO–4.3MgF2 (mol. %) glass and Al2O3 as a filler are provided. Sintered at 875 °C composite ceramics with an initial glass/Al2O3 mass ratio of 60:40 and has ?r = 8.7 and tan ? = 6.6 ·10–4, at frequency 1 MHz. The flexural strength of such ceramics is 117.5 MPa, CTE = 69.7 10–7 K–1, the composite is chemically compatible with silver and can be promising material for the low-temperature of co-fired ceramics technology.
Aram K. Kostanyan – PhD, Head of Laboratory, Institute of General and Inorganic Chemistry of NAS RA, Yerevan, Armenia
Hasmik G. Manukyan – PhD, Senior Researcher, Institute of General and Inorganic Chemistry of NAS RA, Yerevan, Armenia
Karine A. Sargsyan – researcher, Institute of General and Inorganic Chemistry of NAS RA, Yerevan, Armenia
Gohar S. Karakhanyan – researcher, Institute of General and Inorganic Chemistry of NAS RA, Yerevan, Armenia
Hovakim A. Alexanyan – junior researcher, Institute of Applied Problems of Physics of NAS RA, Yerevan
Nikolay B. Knyazyan – Doctor of Science, Head of Laboratory, Institute of General and Inorganic Chemistry of NAS RA, Yerevan, Armenia
1. Sebastian M. T., Jantunen H. Low loss dielectric materials for LTCC applications // Inter. Mater. Rev. 2008. V. 53. P. 57 – 90.
2. Luo X., Tao H., Li P., et al. Properties of borosilicate glass/Al2O3 composites with diferent Al2O3 concentrations for LTCC applications // Journal of Materials Science: Materials in Electronics. 2020. V. 31. P. 14069 – 14077.
3. Induja I. J., Surendran K. P., Varma M. R., Sebastian M. T. Low ?, low loss alumina-glass composite with low CTE for LTCC microelectronic applications // Ceramics Int. 2017. V. 43, Is. 1, Part A. P. 736 – 740.
4. Xia Q., Zhong C. W., Luo J. Low temperature sintering and characteristics of K2O–B2O3–SiO2–Al2O3 glass/ceramic composites for LTCC applications // J. Mater. Sci. Mater. Electron. 2014. V. 25(10). P. 4187 – 4192.
5. Zeng D., Xu J., Chen Y., et al. Novel lead free glass/ ceramics system with low permittivity, low loss for LTCC application // Int. J. Appl. Ceram. Technol. 2015. V. 12. P. 112 – 116.
6. Jean J.-H., Lin S.-C. Effects of borosilicate glass on densification and properties of borosilicate glass + TiO2 ceramics // J. Mater. Res. 1999. V. 14. P. 1359 – 1363.
7. Liu M., Zhou X., Zhu X., et al. Low temperature sintering and dielectric properties of Ca–Ba–Al–B–Si–O glass/Al2O3 composites for LTCC applications // Journal of Wuhan University of Technology-Mater. Sci. Ed. 2013. V. 28. P. 1085 – 1090.
8. Chen X., Zhang W., Bai S., Du Y. Densification and characterization of SiO2–B2O3–CaO–MgO glass/Al2O3 composites for LTCC application // Ceramics Int. 2013. V. 39, Is. 6. P. 6355 – 6361.
9. Liu M., Zhou H., Zhu H., et al. Microstructure and dielectric properties of glass/Al2O3 composites with various low softening point borosilicate glasses // J. Mater Sci: Mater Electron. 2012. V. 23. P. 2130 – 2139.
10. Chen S., Zhu D. Phase formation and properties of the BaO–B2O3–SiO2 and –Al2O3 ceramics prepared via an aqueous suspension route // Journal of Alloys and Compounds. 2012. V. 536. P. 73 – 79.
11. Yan T., Zhang W., Chen X., et al. Sintering densification behaviors and crystallization characteristics of glass–ceramics formed by two types of CaO–B2O3–SiO2 glass // Journal of Materials Science: Materials in Electronics. 2019. V. 30. P. 10352 – 10359.
12. Chen X., Zhang W., Bai S., Du Y. Densification and characterization of SiO2–B2O3–CaO–MgO glass/Al2O3 composites for LTCC application // Ceram. Int. 2013. V. 39. P. 6355 – 6361.
13. Luo X. F., Ren L. C., Xie W. T. Microstructure, sintering and properties of CaO–Al2O3–B2O3–SiO2 glass/Al2O3 composites with different CaO contents // J. Mater. Sci. Mater. Electron. 2016. V. 27(5). P. 5446 – 5451.
14. Li E., Zhang P., Duan S., et al. Low temperature sintering behavior of 11Li2O–3Nb2O5–12TiO2 microwave dielectric ceramics // J. Mater. Sci: Mater. Electron. 2015. V. 26. Р. 8398 – 8403.
15. Zhu H., Liu M., Zhou H., et al. Preparation and properties of low temperature co-fired ceramic of CaO–SiO2–B2O3 system // J. Mater. Sci: Mater. Electron. 2006. V. 17. P. 637 – 641.
16. Киприанов А. А., Карпухина Н. Г. Оксигалогенидные силикатные стекла // Физика и химия стекла. 2006. Т. 32, № 1. С. 3 – 40.
17. Князян Н. Б. Неорганические оксифторборатные стекла // Химический журнал Армении. 2017. Т. 70, № 4. С. 499 – 521.
18. Mukherjee D. P., Das S. K. Synthesis and characterization of machinable glass-ceramics added with B2O3 // Ceramics International. 2014. V. 40, Is. 8, Part A. P. 12459 – 12470.
19. Kostanyan A. K., Knyazyzn N. B. Oxyfluoride glasses as a basis for obtaining multilayer co-fired glass-ceramic materials // Chemical Journal of Armenia. 2020. V. 73, No. 4. P. 318 – 329.
20. Свойства и разработка новых оптических стекол. Л.: Изд-во «Машиностроение», 1977. 216 с.
21. Князян Н. Б. Неорганические оксифторидные боратные стекла // Химический журнал Армении. 2017. Т. 70, № 4. С. 49 – 521.
22. URL: www.almatis.com
23. German R. M., Suri P., Park S. J. Review: liquid phase sintering // J. Mater. Sci. 2009. V. 44. P. 1 – 39.
24. Zawrah M. F., Hamzawy E. M. A. Effect of cristobalite formation on sinterability, microstructure and properties of glass/ceramic composites // Ceram. Int. 2002. V. 28, Is. 2. P. 123 – 130.
25. Induja I. J., Abhilash P., Arun S., et al. LTCC tapes based on Al2O3–BBSZ glass with improved thermal conductivity // Ceramics International. 2015. V. 41, Is. 10, Part A. P. 13572 – 13581.

The article can be purchased
electronic!

PDF format

700

DOI: 10.14489/glc.2025.02.pp.055-061
Article type: Research Article
Make a request

Keywords

Use the reference below to cite the publication

Kostanyan A. K., Manukyan H. G., Sargsyan K. A., Karakhanyan G. S., Alexanyan H. A., Knyazyan N. B. Composite material based on oxyfluoride barium boroaluminosilicate glass and Al2O3 for LTCC technology. Steklo i keramika. 2025:98(2):55-61. (in Russ). DOI: 10.14489/glc.2025.02.pp.055-061