The work is devoted to the issues of obtaining thermal insulation materials using local mineral resources. The focus of this study is to create refractory thermal insulation consisting of a porous filler in the form of expanded rocks (hydrophlogopite, perlite) using the technology of ceramic or ceramic-chemical binders based on clay raw materials of varying fire resistance and plasticity. The study of structural changes in the obtained materials understep by step raised temperature conditions was carried out using X-ray phase and microprobe analysis. Analysis of the results showed that the density of hydrophlogopite-based samples on a clay-phosphate binder increases by 30…35 % compared to samples on a ceramic binder. In samples with perlite filler, the introduction of a phosphate binder does not have a significant effect on the apparent density. Pre-synthesized clay phosphate binder on red-burning clay, introduced into the initial perlite mixtures, allows increasing the strength of samples by 2 times without increasing density and thermal conductivity. A study of changes in the strength characteristics of perlite ceramic samples on various phosphate binders in the temperature range of 300…950 ?С showed the stability of the material in strength up to 800 ?С, which indirectly characterizes the transformation of the structure and its operating temperature. Based on the compositions “expanded hydrophlogopite-secondary Samarkand kaolin” and “expanded perlite-secondary Samarkand kaolin-clay phosphate binder on red-burning clay”, thermal insulation materials with improved thermomechanical properties for operating temperatures of 850…1100 ?С were obtained by the method of semi-dry pressing.
Marina Kh. Rumi – PhD, senior researcher, Laboratory of Heat-Accumulating, Heat-Insulating Materials and Solar Technologies, Institute of Materials Science of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
Shahlo K. Irmatova – junior researcher, Laboratory of Heat-Accumulating, Heat-Insulating Materials and Solar Technologies, Institute ofMaterials Science of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
Zulayho R. Kadyrova – Doctor of Chemical Sciences, Professor, head of Laboratory Chemistry and Chemical Technology of Silicates, Institute of General and Inorganic Chemistry of the Academy of Sciences of the Republic of Uzbekistan,Tashkent, Republic of Uzbekistan
Ella M. Urazaeva – junior researcher, Laboratory of Heat-Accumulating, Heat-Insulating Materials and Solar Technologies, Institute of Materials Science of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
Shavkat R. Nurmatov – PhD, deputy of science, Institute of Materials Science, Academy of Sciences of Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
Mars A. Zufarov – junior researcher, Laboratory of Heat-Accumulating, Heat-Insulating Materials and Solar Technologies, Institute of Materials Science of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
Elvira P. Mansurova – junior researcher, Laboratory of Heat-Accumulating, Heat-Insulating Materials and Solar Technologies, Institute of Materials Science of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
Zhakhongir K. Ziyovaddinov – junior researcher, Laboratory of Heat-Accumulating, Heat-Insulating Materials and Solar Technologies, Institute of Materials Science of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
1. Suvorov S. A., Skurikhin V. V. High-temperature thermal insulation materials based on vermiculite // Refractories and technical ceramics. 2002. No. 12. P. 39 – 44. URL: https://link.springer.com/article/10.1023/A:1023449128786
2. Бархатов В. Н., Добровольский И. П., Капкаев Ю. Ш. Отходы производств и потребления. Челябинск: Изд-во Челяб. гос. ун-та, 2017. 477 с. URL: https://rusneb.ru/catalog/000200_000018_RU_NLR_BIBL_A_011711658/
3. Georgiev A., Yoleva A., Djambazov S., et al. Еffect of expanded vermiculite and expanded perlite as pore forming additives on the physical properties and thermal conductivity of porous clay bricks // Journal of Chemical Technology and Metallurgy. 2018. V. 53, Nо. 2. P. 275 – 280. URL: https://journal.uctm.edu/node/j2018-/14_17_76_p_275_280.pdf
4. Sutcu M. Influence of expanded vermiculite on physical properties and thermal conductivity of clay bricks // Ceramics International. 2015. V. 41. Р. 2819 – 2828.URL: https://doi.org/10.1016/J.CERAMINT.2014.10.102
5. Формованные теплоизоляционные изделия из перлита [Электронный ресурс]. URL: https://www.vekha.ru/formovannyeteploizolyacionnye-izd
6. Пат. RU 2365561C1. Масса для изготовления огнеупорных теплоизоляционных материалов и изделий / Айзикович О. М., Василевицкий Я. М., Дерягин В. Б., Сапелкин В. С., Фролов В. П. № 2007145633/03; заявл. 11.12.2007; опубл. 27.08.2009, Бюл. № 24. URL: https://patents.google.com/patent/RU2365561C1/ru
7. Zhan Bing Li, Xiu Wen Wu, Xiao Chao Chen.Effect of fly ash on thermal and mechanical properties of expanded perlite insulation product // Appl. Mech. Mater. 2012. V. 204 – 208. P. 4151 – 4155. URL: https://doi.org/10.4028/www.scientific.net/AMM.204-208.4151
8. Li L., Teng W., Zhang J., et al. Effect of surface vitrification on the properties of insulation board of expanded perlite // Key Eng. Mater. 2017. V. 26. P. 586 – 590. URL: https://doi.org/10.4028/www.scientific.net/KEM.726.586
9. Maaloufa Y., Mounir S., Khabbazi A., et al. Thermal characterization of materials based on clay and granular: cork or expanded perlite // Energy Procedia. 2015. V. 74. P. 1150 – 1161. URL: https://www.sciencedirect.com/science/article/pii/S1876610215015258
10. Апанасевич Н. С., Сокол А. А., Кудлаш А. Н. и др. Термостойкие теплоизолирующие композиционные материалы на основе полых микросфер и твердых фосфатных связующих: разработка и исследование // Журнал Белорусского государственного университета. Химия. 2022. № 2. С. 70 – 82. URL: https://doi.org/10.33581/2520-257X-2022-2-70-82
11. Rumi M. Kh., Urazaeva E. M., Irmatova Sh. K., et al. Sintering characteristics and thermal properties of porous ceramic based on hydrophlogopite and refractory clays // Glass and Ceramics. 2023. V. 80, No. 1–2. P. 45 – 51.URL: http://dx.doi.org/10.1007/s10717-023-00555-z
12. Rumi M. Kh., Urazaeva E. M., Nurmatov Sh. R., et al. Mineralogical aspects of expanded vermiculite ores // Glass and Ceramics. 2023. V. 79, Nо. 9–10. P. 386 – 392. DOI: 10.1007/s10717-023-00518-4
13. Rumi M. Kh., Urazaeva E. M., Nurmatov Sh. R., et al. Study of structural and technological properties of expanded vermiculite during preparation of high-temperature heat insulation // Refractories and Industrial Ceramics. 2022. V. 63(3). Р. 283 – 290. URL: https://doi.org/10.1007/s11148-022-00725-6
14. Rumi M. Kh., Urazaeva E. M., Irmatova Sh. K., et al. Influence of heat treatment on the structure and properties of ceramic heat-insulating composites based on phosphate bound expanded perlite-expanded clay // Open Ceram. 2023. V. 14. Р. 100344. URL: https://doi.org/10.1016/j.oceram.2023.100344
15. Rumi M. Kh., Irmatova Sh. K, Faiziev Sh. A., et al. Production of the aluminosilicate ceramic materials using fly ash from thermal power plants (tpp) // Refractories and Industrial Ceramics. 2020. V. 61, No. 3. Р. 281 – 284. URL: http://dx.doi.org/10.1007/s11148-020-00472-6
16. Mason B. Principles of Geochemistry. New York: John Wiley & Sons Inc, 1966. 329 p. URL: https://openlibrary.org/books/OL18868236M/Principles_of_geochemistry
17. ГОСТ 21521–76. Изделия перлитокерамические теплоизоляционные. М.: Издательство стандартов, 1981.
18. Khlystov A. I., Isaev D. I. Phosphate linking of mineral thin-molted industrial waste // Urban Construction and Architecture. 2019. V. 9(4). P. 85 – 91. DOI: 10.17673/Vestnik.2019.03.11 https://www.researchgate.net/publication/338760154_Phosphate_Linking_of_Mineral_Thin-Molted_Industrial_Waste
19. Arun S. Wagh. Iron phosphate ceramic in chemically bonded phosphate ceramics (second edition), 2016, ELSEVIER, Amsterdam, Netherlands. URL: https://www.sciencedirect.com/topics/engineering/chemically-bonded-phosphate-ceramic
20. Louati S., Baklouti S., Samet B. Geopolymers based on phosphoric acid and illito-kaolinitic clay // Advances in Materials Science and Engineering. V. 2016. Art. 2359759. URL: https://doi.org/10.1155/2016/2359759
21. Абдрахимов В. З., Абдрахимова Е. С. Жаростойкий бетон на основе ортофосфорной кислоты, отходов цветной металлургии и химической промышленности // Construction and Geotechnics. 2021. Т. 12, № 1. С. 72 – 85. DOI: 10.15593/2224-9826/2021.1.06
22. Wagh A., Jeong S., Singh D., et al. Iron-phosphate-based chemically bonded phosphate ceramics for mixed waste stabilization // Proc. Waste Management Annual Meeting, Session 29, Tucson, AZ, March 2 – 6. 1997. URL: https://digital.library.unt.edu/ark:/67531/metadc681372/
23. Zhou L., Peng T., Sun H., et al. A novel separation method of the valuable components for activated clay production wastewater // Open Chemistry. 2021. V. 19. P. 530 – 540. URL: https://doi.org/10.1515/chem-2021-0052
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