This study focuses on the sustainable utilization of shoushan stone mineral processing waste in glaze materials, exploring its synergistic effects on regulating the coloration mechanism and optimizing glaze layer performance. Through single-factor experiments, the impact of varying shoushan stone incorporation levels on ceramic properties was systematically analyzed. Techniques such as XRD, SEM, EDS, and XPS were employed to investigate the effects of shoushan stone on glaze layer structure, Cu ion valence states, and color performance. The results demonstrate that incorporating 10 wt. % shoushan stone significantly enhances the density and glossiness of the glaze layer, promotes the stable presence of Cu??, and induces phase separation structures, thereby improving the color purity and stability of blue glazes. Physicochemical performance tests indicate that the glaze layer exhibits excellent thermal shock resistance, mechanical strength, and environmental friendliness. The SiO?, Al?O?, K?O, and CaO abundant in shoushan stone provide superior fluxing and network regulation effects, confirming its feasibility as a blue glaze raw material. This study presents a novel approach to the high-value utilization of mineral waste, with significant theoretical and practical implications for the sustainable manufacturing of ceramic glazes.
Lai Huasheng – Doctor, Product Design Department, College of Fine Arts and Design, Quanzhou Normal University, Quanzhou, PR, China; Universiti Sains Malaysia, Penang, Malaysia
Deng Weibin – lecturer, Product Design Department, College of Fine Arts and Design, Quanzhou Normal University, Quanzhou, PR, China
Bao Qifu – Doctor, Inorganic Non-Metallic Material Engineering, School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen, PR, China
Lin Zeqin – Doctor, Product Design, Concord University College Fujian Normal University, Fuzhou, PR, China
1. Feng L., Wang F., Luo H., et al. Phase-separated Tenmoku 'Blue' glaze: microstructure and coloring mechanism // Journal of the European Ceramic Society. 2023. V. 43, No. 14. P. 6581 – 6589.
2. Gol F., Yilmaz A., Kacar E., et al. Reuse of glass waste in the manufacture of ceramic tableware glazes // Ceramics International. 2021. V. 47, No. 15. P. 21061 – 21068.
3. Gol F., Saritas Z. G., C?buk S., et al. Coloring effect f iron oxide content on ceramic glazes and their comparison with similar waste-containing materials // Ceramics International. 2022. V. 48, No. 2. P. 2241 – 2249.
4. Gupta A., Gupta N., Saxena K. K., Goyal S. K. Investigation of the mechanical strength of stone dust and ceramic waste based composite // Materials Today. Proceedings, 2020. V. 44. P. 29 – 33.
5. Israil L. I. Mechanical and microstructural properties of opaque ceramic tiles glazed with some industrial wastes // Glass and Ceramics. 2022. V. 79, No. 7. P. 340 – 347.
6. Li Y. J. Mineral composition and characteristics of Shoushan stone // Fujian Geology. 2005. No. 2. P. 79 – 89.
7. Li Y., Zhu L., Xu W., et al. Stratigraphic section and geochronological studies of the Shoushan basin, Fujian province, South China, and its implications for the mineralization of Shoushan stone // Minerals. 2022. V. 12, No. 12. P. 1542.
8. Liu W. D., Jiang G. J., Xu J. Y., et al. XRD study on the mineral composition and classification of Shoushan stone // Journal of Shanghai Institute of Technology (Natural Science Edition). 2009. No. 3. P. 175 – 178.
9. Bayer Ozturk Z., Dal S. Characterization of industrial ceramic glazes containing chromite processing waste: Experimental factorial design effects on color parameters // Materials Chemistry and Physics. 2022. V. 282. P. 125928.
10. Papulova G. N., Kvasnikov M. Y. Development of compositions of pigmented colored lead-free glazes for improving ceramic product design // Glass and Ceramics. 2021. V. 78, No. 3. P. 129 – 132.
11. Rybak J., Gorbatyuk S. M., Bujanovna-Syury-un K. C., et al. Utilization of mineral waste: A method for expanding the mineral resource base of a mining and smelting company // Metallurgist. 2021. V. 64, No. 9. P. 851 – 861.
12. Sang Z., Fu X., Wu M., et al. Study on the coloring mechanism of longquan light greenish-blue celadon glaze from the Southern Song and Yuan Dynasties // Ceramics International. 2023. V. 49, No. 8. P. 13249 – 13257.
13. Soundarya N. Experimental study on the durability properties of Shahabad stone waste as partial replacement of coarse aggregate in concrete // Materials Today. Proceedings, 2020. V. 47. P. 4630 – 4635.
14. Wang C., Liu K., Chen X., et al. Influence of the thickness of the copper glaze layer on the color and its formation mechanism: materials research express. 2022. V. 9, No. 8. P. 085001.
15. Wang Y., Yu S., Tong M., et al. Deciphering the formation mechanism of ancient jun wares copper red and blue glazes // Journal of Cultural Heritage. 2021. V. 48. P. 29 – 35.
16. Li H., Fang Y., Bao Q. F., et al. Effect of Fe?O? and MnO? content on the glaze color of Jilan glaze // Jiangsu Ceramics. 2023. No. 3. P. 38 – 41.
17. Dong W. X., Liang Y., Liu H. Y., et al. Development of Jilan glaze // Ceramics. 2020. No. 8. P. 38 – 41.
18. Wang H. W. Copper-based blue glaze: pioneering a new era of ceramic craft aesthetics (part 1) // Ceramic Science and Art. 2019. No. 3. P. 4 – 9.
19. Yang Z. H., Gao S. Y., Wang F., et al. Effect of iron oxide on the structure and coloration of Jun porcelain opalescent blue glaze // China Ceramics. 2021. No. 4. P. 62 – 67.
20. Wu J. M., Zhang M. L., Li Q. J., et al. Composition and chromaticity characteristics of Jilan glaze in Ming and Qing dynasty official kilns // Spectroscopy and Spectral Analysis. 2012. No. 8. P. 2254 – 2259.
21. Liu H. G., Zeng X. T., Liao W. J., et al. Preliminary study on imitating Shiwan Guangjun blue glaze using common raw materials // China Ceramic Industry. 2017. No. 4. P. 10 – 16.
22. Yuan M., Hou J., Zhang X., et al.Changsha ware glaze color: composition, nanostructure, and copper and iron speciation // Journal of the American Ceramic Society. 2024. V. 107, No. 11. P. 7577 – 7593.
23. Svarcova S., Hradil D., Hradilova J., Cermakova Z. Pigments – copper-based greens and blues // Archaeological and Anthropological Sciences. 2021. V. 13, No. 11. P. 190.
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DOI: 10.14489/glc.2025.10.pp.055-064
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