Monolithic samples of functionally graded ceramic materials were fabricated via reaction sintering (siliconizing) of silicon carbide and diamond powders. The resulting materials are layered composites bonded by a continuous silicon carbide matrix through a reaction-diffusion mechanism. Structural characterization and physicomechanical testing of the multilayer ceramics were performed on prototype samples. The microstructural features of reaction-bonded materials based on silicon carbide and diamond–silicon carbide composites, both as monoliths and within multilayer architectures, are experimentally described. Recommendations are provided regarding the potential applications of functionally graded silicon-carbide-based ceramics with diamond particles in specialized engineering fields.
Mikhail A. Markov – Doctor of Technical Sciences, deputy head of the Laboratory "Technical Ceramics", National Research Center "Kurchatov Institute" – Central Research Institute of Structural Materials "Prometey", St. Petersburg, Russia
Anton N. Belyakov – Candidate of Technical Sciences, senior research fellow, National Research Center "Kurchatov Institute" – Central Research Institute of Structural Materials "Prometey", St. Petersburg, Russia
Alina D. Bykova – Candidate of Technical Sciences, head of the Laboratory "Technical Ceramics", National Research Center "Kurchatov Institute" – Central Research Institute of Structural Materials "Prometey", St. Petersburg, Russia
Margarita A. Glebova – engineer, National Research Center "Kurchatov Institute" – Central Research Institute of Structural Materials "Prometey", St. Petersburg, Russia
Alexey V. Ilyin – Doctor of Technical Sciences, chief researcher, National Research Center "Kurchatov Institute" – Central Research Institute of Structural Materials "Prometey", St. Petersburg, Russia
Daria A. Dyuskina – engineer of the 2rd category, National Research Center "Kurchatov Institute" – Central Research Institute of Structural Materials "Prometey", St. Petersburg, Russia
Alexander D. Kashtanov – Doctor of Technical Sciences, advisor to the general director, National Research Center "Kurchatov Institute" – Central Research Institute of Structural Materials "Prometey", St. Petersburg, Russia
Andrey G. Chekuryaev – engineer of the 2rd category, National Research Center "Kurchatov Institute" – Central Research Institute of Structural Materials "Prometey", St. Petersburg, Russia
Alexander N. Nikolaev – Candidate of Technical Sciences, senior research fellow, National Research Center "Kurchatov Institute" – Central Research Institute of Structural Materials "Prometey", St. Petersburg, Russia
1. Erasenthiran P., Beal V. E. Functionally graded materials // Rapid Manufacturing: An Industrial Revolution for the Digital Age. 2006. P. 103 – 124. DOI: 10.1002/0470033991
2. Naebe M., Shirvanimoghaddam K. Functionally graded materials: A review of fabrication and properties // Applied Materials Today. 2016. V. 5. P. 223 – 245. DOI: 10.1016/j.apmt.2016.10.001
3. Saleh B., Jiang J., Fathi R., et al. 30 Years of functionally graded materials: An overview of manufacturing methods, applications and future challenges // Composites Part B: Engineering. 2020. V. 201. P. 108376. DOI: 10.1016/j.compositesb.2020.108376
4. Назаренкова А. А., Половинкин Н. С. Разработка функционально-градиентных материалов // Теория и практика современной науки. 2019. № 1(43).
5. El-Galy I. M., Saleh B. I., Ahmed M. H. Functionally graded materials classifications and development trends from industrial point of view // SN Applied Sciences. 2019. V. 1, No. 11. DOI: 10.1007/s42452-019-1413-4
6. Gordienko A. I., Ivashko V. V., Vegera I. I. Development and application of functionally graded materials // Bulletin of P. O. Sukhoi Gomel State Technical University. 2007. No. 2(29). P. 51 – 57.
7. Gerashchenkov D. A., Makarov A. M., Bystrov R. Y., et al. Technological aspects of obtaining functional gradient coatings to protect machinery from wear // Key Engineering Materials. Switzerland. 2019. V. 822. P. 768 – 773. DOI: 10.4028/www.scientific.net/KEM.822.768
8. Nikolaev A. N., Ban'kovskaya I. B., Perevislov S. N. Influence of nanosized zirconiumand aluminum-oxide particles on the properties of Si–B4C–ZrB2 composite materials // Refractories and Industrial Ceramics. 2020. V. 61, No. 4. P. 428 – 432. DOI: 10.1007/s11148-020-00498-w
9. Gerashchenkova E. Yu., Markov M. A., Gerashchenkov D. A., et al. Investigation of aspects of compensation for thermal expansion of 3D gradient materials Al–Al2O3 using "cold" spraying technology // Metallurgist. 2025. V. 69, No. 4. P. 510 – 520. DOI: 10.1007/s11015-025-01968-7
10. Bhavar V. A., Kattire P., Thakare S. Review on functionally gradient materials (FGMs) and their applications // 4th Int. Conf. on Mechanics and Mechatronics Research, IOP Conf. Series: Materials Science and Engineering. 2017. V. 229(1). Р. 012021.
11. Гнесин Г. Г. Карбидокремниевые материалы. М.: Металлургия, 1977. 216 с.
12. Belyakov A. N., Markov M. A., Kravchenko I. N., et al. Contemporary materials and their application in the construction of special engineering high-temperature objects // Refractories and Industrial Ceramics. 2023. V. 64, No. 3. P. 256 – 264. DOI: 10.1007/s11148-024-00835-3
13. Markov M. A., Krasikov A. V., Kravchenko I. N., et al. Development of novel ceramic construction materials based on silicon carbide for products of complex geometry // Journal of Machinery Manufacture and Reliability. 2021. V. 50, No. 2. P. 158 – 163. DOI: 10.3103/S1052618821020096
14. Belyakov A. N., Markov M. A., Kravchenko I. N., et al.Structural and physicomechanical properties of silicon carbide-based reaction-sintered ceramics // Russian Metallurgy (Metally). 2024. V. 2024, No. 7. P. 1536 – 1543. DOI: 10.1134/S0036029524702720
15. Taya M., Hayashi S., Kobayashi A. S., Yoon H. S. Toughening of a particulate reinforced ceramic-matrix composite by thermal residual stress // Journal of the American Ceramic Society. 1990. No. 73. Р. 1382 – 1391. DOI: 10.1111/j.1151-2916.1990.tb05209.x
16. Belyakov A. N., Markov M. A., Chekuryaev A. N., et al. Investigation of the reaction-sintered B4C–SiC materials produced by hot slip casting // Glass Physics and Chemistry. 2023. V. 49, No. 3. P. 306 – 313. DOI: 10.1134/S1087659623600060
17. Bucevac D., Krstic V. Microstructure–mechanical properties relations in SiC–TiB2 composite // Materials Chemistry and Physics. 2012. V. 133, No. 1. Р. 197 – 204. DOI: 10.1016/j.matchemphys.2012.01.007
18. Ruys A. J. Silicon carbide ceramics structure, properties, and manufacturing. Elsevier, 2023. 585 p.
19. Гордеев С. К., Ежов А. Ю., Каримбаев Т. Д. и др. Дисперсно-упрочненные композиции «алмаз–карбид кремния» – новые материалы для машиностроения // Композиты и наноструктуры. 2015. Т. 7, № 2(26). С. 61 – 71.
20. Gordeev S. K., Korchagina S. B., Zapevalov V. E., et al. Diamond–silicon carbide composite as a promising material for microelectronics and high-power electronics // Radiophysics and Quantum Electronics. 2022. V. 65, No. 5–6. Р. 434 – 441.
21. Гордеев С. К. Алмазокарбидокремниевые композиционные материалы АКК «Скелетон» // Вопросы материаловедения. 2024. № 1(117). С. 99 – 116.
22. Каримбаев Т. Д., Мезенцев М. А., Мыктыбеков Б. и др. Карбид кремния, дисперсно-армированный алмазными частицами – АКК «Скелетон» – для элементов высокотемпературных узлов // Композиты и наноструктуры. 2023. Т. 15, № 4. С. 273 – 283.
23. Shevchenko V. Ya., Makogon A. I., Sychov M. M., et al.Reaction–diffusion pathways for a programmable nanoscale texture of the diamond–SiC composite // Langmuir. 2022. No. 38(49). Р. 15220 – 15225.
24. Shevchenko V. Y., Perevislov S. N., Kovalchuk M. V., Oryshchenko A. S. New chemical technologies based on turing reaction–diffusion processes // Doklady Chemistry. 2021. V. 496, No. 2. Р. 28 – 31.
25. Belyakov A. N., Markov M. A., Kashtanov A. D., et al. Ballistic performance of diamond–silicon carbide composite fabricated by reaction sintering // Glass and Ceramics. 2026. V. 82, No. 9–10. P. 356 – 362. DOI: 10.1007/s10717-026-00799-5
26. Shevchenko V. Ya., Oryshchenko A. S., Belyakov A. N., Perevislov S. N. Determination of the mechanical characteristics of the ideal ceramic (diamond–silicon carbide composite) // Glass Physics and Chemistry. 2023. V. 49, No. 6. P. 539 – 543. DOI: 10.1134/s108765962360062x
27. Belyakov A. N., Markov M. A., Dyuskina D. A., et al. A comparative study of methods for obtaining silicon carbide ceramic materials // Refractories and Industrial Ceramics. 2023. V. 64, No. 3. P. 299 – 310. DOI: 10.1007/s11148-024-00842-4
28. Markov M. A., Vikhman S. N., Belyakov A. N., et al. High-temperature bending tests of reaction-sintered silicon carbide-based ceramic materials // Russian Journal of Applied Chemistry. 2023. V. 96, No. 1. P. 16 – 20. DOI: 10.1134/S1070427223010032
29. Марков М. А., Дюскина Д. А., Николаев А. Н. и др. Определение трибологических характеристик алмазной керамики в паре трения с конструкционными материалами // Новые огнеупоры. 2025. № 5. С. 24 – 32.
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