Polymorphic transitions in Al 2 O 3, tungsten bronzes, 2CaO x SiO 2, ZrO 2 are considered. Since oxides usually have an excess of oxygen vacancies at high temperatures, a further increase in their concentration due to the introduction of appropriate additives slows down diffusion, prevents the polymorphic transition, and stabilizes the phase. The introduction of additives leading to an increase in the concentration of vacancies in the cation, on the contrary, accelerates diffusion and promotes the polymorphic transition. Bibliography: 10 titles.